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What
are the primary types of filter
vessels?
There are three primary types of filter vessels; Plastic,
Steel and Fiberglass Reinforced Polymer Plastic (FRP). Plastics
and Steel tend to work best in situations that can accommodate
a shorter life span in a non-corrosive environment. However,
both materials quickly break down over time, especially in
corrosive environments. In other words, steel rusts; FRP doesn’t.
In certain corrosive conditions, a carbon steel vessel might
last 1 year and a 316 stainless steel vessel might last 3
year. An FRP vessel, however, is likely to last 15 years or
more. All steel structures will eventually deteriorate due
to galvanic corrosion. The ionic exchange that occurs removes
metal ions from steel structures and leads to leakage or explosive
structural failure. This is due to the fact that like all
metals, steel contains crystals. FRP does not suffer from
galvanic corrosion. This is because FRP is a polymeric composite
made from continuous filaments of glass (not crystals) that
are individually coated with a thermosetting resin matrix
that bonds them tightly together. In fact, glass is actually
a super-cooled liquid that becomes increasingly hard and strong
as its viscosity increases when its temperature is decreased
from its 12,700 C. melting point.
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Why
did the filtration industry move to FRP vessels and tanks?
Thirty
years ago saw the beginning of FRP pressure vessels and tanks.
These were made the same way as today – layering fiberglass
or carbon fibers with various resins. The material was as
light as magnesium and stronger than carbon steel. When used
as pipe material, one pound of this filament reinforced plastic
(FRP) was able to replace 8 to 12 pounds of steel. The most
commonly used corrosion-resistant resins were those of the
polyester family. In extremely corrosive chemical environments,
a stronger, more corrosion-resistant resin was needed; one
that would stand up to not only highly corrosive materials
such as hydrochloric acid and sulfuric acid but also resist
the high stress and cyclic loading placed on pressure vessels.
Dow Chemical
hypothesized that the addition of an epoxy backbone would
greatly increase the resistance dilemma. The strength and
toughness of the epoxy would make the resin highly resistant
to chemicals and solvents. Then, to enhance the reactivity
of the resin, vinyl acrylate groups could be placed on this
epoxy backbone. The result, Dow Derakane 411 epoxy vinyl ester
resin, which gives broader corrosion and solvent resistance
than older established polyester resins. It has been designed
for 10 to 20 percent more laminate strength, 2 to 4 times
better adhesion and 3 to 5 times greater elongation than other
resins. Chemical attack on these types of resins occurs through
hydrolysis of the ester groups or the splitting of unreacted
carbon-to-carbon double bonds through actions such as oxidation
or halogenation. If the laminate layer of a polyester resin
cracks, chemicals can seep in through the corrosion barrier
and destroy the laminate. Without going into a detailed chemical
lecture, the vinyl groups of polyester resins are dispersed
throughout a molecular chain. This results in cross-linking
and brittleness. Derakane epoxy vinyl ester resins place the
double bonds at the end of the molecular chain. These react
completely on polymerization, resulting in a more chemically
resistant structure. With these bonds confined to the ends
of the molecules the entire length of the molecular chain
is able to elongate under stress and absorb mechanical and
thermal stress or shock. This inherent resistance to cracking
means three things:
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When
properly designed for a given load, the wall of an FRP
filter vessel can be made thinner than comparable steel
vessels. |
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When
designed with a tensile strength of 12,000 PSI and a 10:1
safety allowance, laminate made with Derakane 411 resin
shows an actual safety factor of 16:1 or greater while
polyester resin laminates have a safety factor of less
than 7:1. |
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When
designed to an allowable strain of 0.1 percent, the laminate
made with Derakane 411 resin has a true safety allowance
of greater than 11:1 compared to 5:1 for the polyester
resin. |
Table
1 presents data on the room temperature properties of 1/8”
thick clear castings of Derakane 411 epoxy vinyl ester resins.
The combination of high clear casting strength plus high elongation
is a good indicator of the toughness of Derakane resins.
TABLE
1
Comparison
of room temperature properties of Derakane resins |
| Tensile
Strength, psi |
11
- 12,000 |
| Tensile
Modulus, psi x 105 |
4.9 |
| Elongation
% |
5.0 - 8.0 |
| Flexural
Structure, psi |
16
- 18,000 |
| Flexural
Modulus, psi x 105 |
4.5 |
| Heat
Distortion Temp., 0F |
210
- 220 |
| Barcol
Hardness |
35 |
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How
is the filter vessel constructed?
Eden Equipment Company has employed the advantages of the
Dow Derakane epoxy vinyl ester resin and used its inherent
strength and corrosion resistance to provide a filter vessel
that is a superior choice for a wide variety of uses. Eden
Equipment Company’s line of Excel filter vessels are
available in five sizes ranging from 8 to 30 inches in diameter
with flow rates up to 3,200 gallons per minute.
During the construction of pipe, tanks, or pressure vessels,
filament winding is an automated process that yields a hollow
shape. Typically, the filament winding process involves continuous
glass roving passing through a tensioner and into a resin
bath. From here the saturated glass strands are wound onto
a rotating mandrel at a precisely predetermined angle and
speed. The filaments are collimated and aligned by a proprietary
process that resists both longitudinal and circumferential
stresses imposed by the vessels internal pressure. This patented
process assures dimensional control on the interior sealing
diameters when the vessel is subjected to a wide range of
both temperature and pressure loads.
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What
is the FRP vessel made with?
The FRP vessel is made with a reinforcement of fiberglass
fibers. The reinforcement provides the finished product with
the strength and structure while the resin acts as a corrosion
barrier preventing corrosive elements from penetrating the
FRP material. FRP materials can be stronger than steel on
an equal weight basis (termed “structural efficiency”
or “strength-to-weight” ratio). Optimal strength
can be realized through proper orientation of the glass reinforcement.
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How
are the filter vessels sealed?
FRP filter vessels are designed with side piston seal o-ring
mechanisms similar to that used in automobile engines. This
method of construction actually increases the seal compression
as the pressure in the vessel increases. The vessel is sealed
when the top seal plate is put into place. There is no need
to torque cover bolts to ensure integrity. Mere hand tightening
of the cover bolts is sufficient to provide a leak-proof vessel.
The lower seal plate of the vessel seals with two o-rings
to prevent leakage and maintain the integrity of the clean
and dirty sides of flow.
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Are
filtration vessels resistant to
chemicals?
Filtration vessels constructed of Dow Derakane 411 have excellent
resistance to corrosion by many different chemicals, including
both acids and alkalis. This resistance extends from below
ambient conditions to elevated temperatures. FRP vessels require
little, if any, maintenance during the course of a long service
life. Excel filter vessels are able to operate in the following
fluid and load conditions:
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Internal
pressure – unless otherwise specified a maximum
allowable working pressure of 150 PSI is recommended. |
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Working
fluid – solutions having a pH range from 2 to 13
with solutions of inorganic salts or chemistries deemed
acceptable to Excel filter vessels. |
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Temperature
– ambient or fluid temperatures ranging from 20
to 150º F. |
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How
long does the filter vessel exterior
last?
In addition to the corrosion resistance for the interior of
the filter vessel, Excel filter vessels can be designed with
long exterior life in mind. While there is no direct fluid
contact with the externals of the filter vessel, every aspect
should be well thought out. For example, anodized 6061-T651
aluminum (anodized) and 303 stainless steel can be used for
standard housings. For special applications, all the supporting
externals can be ordered in 316L stainless steel or other
polymers. The steel is certified per ASTM and ASME Codes and
has no welds or weld repairs. Even though there are no metallic
wetted parts; this provides external materials free from mercury
and/or other foreign contaminants. However, this is not always
the case with welded steel vessels. The external fiberglass
may be painted with a modified oil alkyd enamel that has excellent
resistance to weather, salt and sun. In the case of exceptionally
aggressive chemicals, the inside of the vessels may be lined
with either polypropylene or PVDF. These liners are bonded
to the fiberglass to form one integral component. One other
available option is the addition of Benzoyl Peroxide. (BPO)
to the Derakane resin. This high boiling point plasticizer
is used as a catalyst in the polymerization process and halts
runaway decomposition. This application is especially useful
in sodium hypochlorite (bleach) applications.
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Are
the filter vessels pressure tested?
All Excel filter vessels are designed to withstand a cyclic
pressure test comprising a minimum of 100,000 cycles, each
cycle ranging from atmospheric pressure to a maximum use pressure
at a cyclic rate ranging from two to twenty cycles per minute.
The cyclic test fluid is water at a maximum temperature of
1,500º F. The vessels are tested prior to shipment following
ASME Code, Section X test procedures. Each vessel is hydrostatically
tested with water at ambient temperature to a pressure equal
to two times the maximum use pressure. ASME Code requires
the vessel be tested for not less than thirty minutes and
no longer than twenty-four hours. During test procedures no
noticeable pressure drop will be permitted and no leaking
shall occur throughout the tube wall or around the end closure
seals.
Due to
the flexibility of the design, vessels may utilize either
double or single open ended cartridges. Either style will
provide a no by-pass filter vessel with minimal pressure drops.
Along with being highly corrosion resistant to a wide range
of chemicals, Derakane 411 resin complies with the U.S. Food,
Drug and Cosmetic Act as amended and applicable FDA regulations
(21 CFR 177.2120). These resins may be used as articles or
components of articles intended for repeated use in contact
with foodstuffs.
In summary,
the process listed above is designed to provide the customer
a filter housing with unparalleled corrosion resistance, safety
and longevity.
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